Jumat, 06 Februari 2015

Challenges to manufacture of pipe for deepwater, corrosive hydrocarbons


Challenges to manufacture of pipe for deepwater, corrosive hydrocarbons

Richard Freeman - Corus Tubes Energy
Gas is increasingly important in a historically oil-driven world economy. Its increased value is a driver of pipeline technology developments. To meet the demand for gas transportation through more onerous environments, there are factors the pipe and plate makers need to consider to ensure the finished product meets the standards required especially for sour service and deepwater applications.
One trend driving pipeline demand is the gas production from deepwater fields. Traditionally this gas would either be flared or re-injected into the well for enhanced recovery. However, operators now are keen to capture this production and trade it as either liquefied natural gas (LNG) or domestic gas. These gas-gathering prospects present challenging combinations of deepwater installation, corrosive well fluids, and difficult shore approach conditions. These all combine for demanding pipe specifications for manufacturers to meet.
These requirements can be met only with a holistic technical approach from plate procurement to pipe dispatch. The foundation of this approach is to use the highest quality sour plate, which is delivered using state-of-the-art primary and secondary steel making, continuous casting, and proper plate rolling practices. During UOE (U-ing, O-ing, and Expanding) pipe manufacture, the forming process is optimized so strain is managed to minimize any reduction in sour resistance. For these demanding applications, low-temperature toughness in the heat affected zone, demanding hardness, and Battelle drop weight tear test requirements commonly are specified. In combination with forming, welding using optimum consumables and design parameters ensures the mechanical properties and integrity of the pipe.

Gas-gathering in West Africa

Corus recently completed a series of gas-gathering development projects in West Africa to link fields and to transport the gas for export as LNG. In total, the company supplied 81,000 metric tons (89,287 tons) of thick-walled, sour-resistant steel linepipe to three projects
The pipe, ranging from 457 mm (18 in.) to 610 mm (24 in.) in diameter and up to 33.5 mm (1.3 in.) in wall thickness, is to transport gas in water depths of up to 1,500 m (4,921 ft) over difficult seabed bathymetry and also with critical shore approach areas. Corus exported the pipe from its Hartlepool 42 in. capacity mill in the UK to West Africa where the project is being completed with first gas scheduled for 2012.

Thick-walled sour service pipe manufacturing

Gas lines typically are larger diameter and generally constructed from welded linepipe – the most economical production method. However, for deepwater prospects, the parameters for gas transmission are restricted by the following:
  •      The offshore lay process and the need for speedy, reliable welding restricts the line chemistry to strength grades at X65 or below
  •      Seabed stability restricts the diameter of the line that can be installed – larger diameter pipe is more buoyant and less stable
  •      Larger diameter pipe is more vulnerable to hydrostatic collapse, meaning wall thickness needs to be increased
  •    Wall thickness also needs to be increased because of corrosion concerns and fatigue life considerations.
Corus supplied 81,000 metric tons (89,287 short tons) of thick-walled, sour resistant steel  
linepipe to three projects offshore West Africa.

These reasons drive a need for thicker pipe wall with higher induced strain during forming, but pipe which also conforms to international standards such as DNV, ISO, and API. Successful manufacture of these pipes needs not only an expert understanding of steel and pipe making but also an appreciation of the service demands.

Challenges of pipe forming

During service, the pipe bore is exposed to a wet, sour (H2S) environment. Atomic hydrogen is generated at the pipe surface via a cathodic reaction, and enters the steel. Migrating hydrogen atoms move through the structure, gather and combine with each other at discontinuities, voids, and susceptible zones in the microstructure to produce molecular hydrogen (H2). The increasing quantity of H2 at the initiation site creates a high hydrogen pressure, which can be magnified by the shape of the site, leading to a stress concentration that ultimately “cracks” the microstructure.

Strain compromises sour service phenomena such as hydrogen induced cracking (HIC), and with the industry looking for more stringent sour resistant ratios, pipe milling influence on these factors need to be understood.
Total micro-strain from forming could contribute to an increase in the number of available sites for molecular hydrogen formation throughout the microstructure. Therefore, the effects of compression and expansion may have to be considered as cumulative. Control of these features within the microstructure is essential to ensure the pipe’s sour performance is achieved.
The sour resistance of the plate is imparted via the chemistry and microstructure. Most modern steelmakers agree that to balance the mechanical properties needed with sour resistance, the required microstructure is a very clean, fine-grained, equiaxed/polygonal, or acicular ferrite structure with limited volumes of secondary phases such as an artensite/austenite (M/A) phase.
Fine grained equiaxed/acicularferrite structure.

To deliver optimum sour properties in the final pipe, attention needs to be paid to each stage of the process from steel making to final pipe fabrication. During steel making, the process must be monitored where the material is treated prior to casting with the correct composition, homogeneity, and temperature suitable for HIC resistant quality.
Casting is integral to ensuring sufficient quality for plate rolling to HIC grade. This includes controlling macro-segregation, which occurs as steel transitions from the liquid to the solid phase, achieved through soft reduction, Statistical Process Control, and Caster configuration processes.
In terms of plate rolling, single-phase austenitic rolling is favored to meet the sour service and drop weight tear test (DWTT) requirements of a thick wall for offshore projects. However, recent experience shows that material with a higher proportion of acicular ferrite in the microstructure can be susceptible to a phenomenon known as “inverse fracture” with associated low shear values, which has not been seen previously in bainitic/acicular ferrite structures. A program is under way to understand this behavior and to determine whether DWTT is a viable evaluation of the resistance to long running brittle fracture for these steels.

Pipe making

While the amount of strain imparted to form the pipe is set by dimensions, there are key parameters to consider, specifically strain management when forming and welding.
Control of shape and formability is required to ensure a consistent product; poorly controlled forming leads to variable strain effects within each pipe. The forming in the crimp, U- and O-press, and subsequent expansion must be accurate and consistent to ensure each pipe produced is representative of the pipeline as a whole.
Suitable welding consumables are selected to achieve the weld hardness and toughness requirements, and to deliver good HIC performance across the weld. For toughness, a moderate manganese wire is used with alloying additions of silicon and molybdenum; titanium and boron also can be used, depending on the toughness required. The wire is combined with a high-performance, semi-basic and fully agglomerated flux, which combine to promote formation of acicular ferrite in the weld bead, and confer good Charpy and crack tip opening displacement (CTOD) toughness at low testing temperatures while maintaining a stable welding performance.
In addition to the mechanical performance of the weld, a high level of integrity must be maintained through production. This means low levels of slag entrapment and gas defects, for example, as well as cracks to ensure a clean seam is presented to the welding machine to avoid gas defects. The weld arc and flux burden must be sufficiently stable to minimize slag entrapment.

Future trends

The question remains whether these pipelines will continue to be required as technology offers other methods to transport gas such as FLNG. However, the diversity of the offshore industry almost certainly means a variety of technologies both old and new will be used in the future.
Deploying an FLNG liquefaction vessel directly to a field similar to an FPSO for oil, may remove the need in some instances for gas export pipeline projects, but infield subsea connections still will be needed.
Additionally, regassification and liquefaction are being considered for some applications offshore, opening further pipeline prospects for product transfer from ship to shore. These offshore pipelines are likely to have demanding specifications, crossing high-risk shore approach areas and shallows. Additionally, the increasing trend towards deepwater production means the linepipe must counteract higher concentrations of impurities, driving the need for products to meet severe sour conditions.
03/01/2010

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